Metasomatism is the chemical alteration of a rock In geology, rock is a naturally occurring solid aggregate of minerals and/or mineraloids by hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water; 'hydros' in the Greek meaning water and 'thermos' meaning heat. Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. This generally occurs near volcanic activity, but can occur in the deep crust related to the and other fluids.

Metasomatism can occur via the action of hydrothermal fluids from an igneous Igneous rock is one of the three main rock types, the others being sedimentary and metamorphic rock. Igneous rock is formed through the cooling and solidification of magma or lava. Igneous rock may form with or without crystallization, either below the surface as intrusive (plutonic) rocks or on the surface as extrusive (volcanic) rocks. This or metamorphic Metamorphism is the solid-state recrystallization of pre-existing rocks due to changes in physical and chemical conditions, primarily heat, pressure, and the introduction of chemically active fluids. Mineralogical, chemical and crystallographic changes can occur during this process source.

Metasomatic albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. As such it represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula Na + hornblende Hornblende is a complex inosilicate series of minerals . Hornblende is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. It is an isomorphous mixture of three molecules; a calcium-iron-magnesium silicate, an aluminium-iron-magnesium silicate, and an iron-magnesium silicate + tourmaline Tourmaline is a crystal silicate mineral compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is classified as a semi-precious stone and the gem comes in a wide variety of colors. The name comes from the Sinhalese word "Thuramali" or "Thoramalli" (තෝරමල්ලි), alteration of metamorphosed granite Granite is a common and widely occurring type of intrusive, felsic, igneous rock. Granites usually have a medium to coarse grained texture. Occasionally some individual crystals (phenocrysts) are larger than the groundmass in which case the texture is known as porphyritic. A granitic rock with a porphyritic texture is sometimes known as a porphyry, Stone Mountain Stone Mountain is a quartz monzonite dome monadnock in Stone Mountain, Georgia. At its summit, the elevation is 1,686 feet amsl and 825 feet (251.5 m) above the surrounding area. Stone Mountain granite extends underground 9 miles (14 km) at its longest point into Gwinnett County. Numerous reference books and Georgia literature have dubbed Stone, Atlanta Atlanta is the capital and most populous city in the U.S. state of Georgia

In the igneous Igneous rock is one of the three main rock types (the others being sedimentary and metamorphic rock). Igneous rock is formed by magma or lava (molten rock) cooling and becoming solid. Igneous rock may form with or without crystallization, either below the surface as intrusive (plutonic) rocks or on the surface as extrusive (volcanic) rocks. This environment, metasomatism creates skarns It usually forms by chemical metasomatism of rocks during metamorphism and in the contact zone of magmatic intrusions like granites with carbonate-rich rocks such as limestone or dolostone. Skarns in the igneous environment are associated with hornfels, marble hornfels and wider zones of calc-silicate rocks, greisen, and may affect hornfels Hornfels is the group designation for a series of contact metamorphic rocks that have been baked and indurated by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable in the contact metamorphic aureole adjacent to an intrusive An intrusion is liquid rock that forms under the surface of the earth. Magma from under the surface slowly moves its way up from deep within the earth and moves into any cracks or spaces it can find, sometimes pushing existing country rock out of the way, a process that can take millions of years or more to form. As the rock slowly cools into a rock mass. In the metamorphic environment, metasomatism is created by mass transfer from a volume of metamorphic rock Metamorphic rock is the result of the transformation of an existing rock type, the protolith, in a process called metamorphism, which means "change in form". The protolith is subjected to heat and pressure causing profound physical and/or chemical change. The protolith may be sedimentary rock, igneous rock or another older metamorphic at higher stress In continuum mechanics, stress is a measure of the average force per unit area of a surface within a deformable body on which internal forces act. In other words, it is a measure of the intensity of the internal forces acting between particles of a deformable body across imaginary internal surfaces . These internal forces are produced between the and temperature Historically, two equivalent concepts of temperature have developed, the thermodynamic description and a microscopic explanation based on statistical physics. Since thermodynamics deals entirely with macroscopic measurements, the thermodynamic definition of temperature, first stated by Lord Kelvin, is stated entirely in empirical, measurable into a zone with lower stress and temperature, with metamorphic hydrothermal solutions acting as a solvent A solvent is a liquid, solid, or gas that dissolves another solid, liquid, or gaseous solute, resulting in a solution that is soluble in a certain volume of solvent at a specified temperature. Common uses for organic solvents are in dry cleaning (e.g. tetrachloroethylene), as a paint thinner (e.g. toluene, turpentine), as nail polish removers and. This can be envisaged as the metamorphic rocks within the deep crust In geology, a crust is the outermost solid shell of a rocky planet or moon, which is chemically distinct from the underlying mantle. The crusts of Earth, our Moon, Mercury, Venus, Mars, Io, and other planetary bodies have been generated largely by igneous processes, and these crusts are richer in incompatible elements than their respective mantles losing fluids and dissolved mineral A mineral is a naturally occurring solid chemical substance that is formed through geological processes and that has a characteristic chemical composition, a highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not have a specific chemical composition components as hydrous minerals break down, with this fluid percolating up into the shallow levels of the crust to chemically change and alter these rocks.

This mechanism implies that metasomatism is open system behaviour, which is different from classical metamorphism Metamorphism is the solid-state recrystallization of pre-existing rocks due to changes in physical and chemical conditions, primarily heat, pressure, and the introduction of chemically active fluids. Mineralogical, chemical and crystallographic changes can occur during this process which is the in-situ mineralogical change of a rock without appreciable change in the chemistry of the rock. Because metamorphism usually requires water Water is a chemical substance with the chemical formula H2O. Its molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state, water vapor or steam in order to facilitate metamorphic reactions, metasomatism and metamorphism nearly always occur together.

Further, because metasomatism is a mass transfer process, it is not restricted to the rocks which are changed by addition of chemical elements A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. The term is also used to refer to a pure chemical substance composed of atoms with the same number of protons. Common examples of elements are iron, copper, silver, gold, hydrogen, carbon, and minerals or hydrous compounds A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together in a defined spatial arrangement by chemical bonds. In all cases, to produce a metasomatic rock some other rock is also metasomatised, if only by dehydration reactions with minimal chemical change. This is best illustrated by gold ore deposits The various theories of ore genesis explain how the various types of mineral deposits form within the Earth's crust. Ore genesis theories are very dependent on the mineral or commodity which are the product of focused concentration of fluids derived from many cubic kilometres of dehydrated crust In geology, a crust is the outermost solid shell of a rocky planet or moon, which is chemically distinct from the underlying mantle. The crusts of Earth, our Moon, Mercury, Venus, Mars, Io, and other planetary bodies have been generated largely by igneous processes, and these crusts are richer in incompatible elements than their respective mantles into thin, often highly metasomatised and altered shear zones and lodes In geology, a lode is a deposit of metalliferous ore that fills or is embedded in a fissure in a rock formation or a vein of ore that is deposited or embedded between layers of rock. The source region is often largely chemically unaffected compared to the highly hydrated, altered shear zones, but both must have undergone complementary metasomatism.

Metasomatism is more complicated in the Earth's mantle The mantle is a part of a terrestrial planet or other rocky body large enough to have differentiated by density. The interior of the Earth, similar to the other terrestrial planets, is chemically divided into layers. The mantle is a highly viscous layer between the crust and the outer core. Earth's mantle is a rocky shell about 2,890 km thick that, because the composition of peridotite A peridotite is a dense, coarse-grained igneous rock, consisting mostly of the minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium, reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from the Earth's mantle, either as solid at high temperatures can be changed by infiltration of carbonate In chemistry, a carbonate is a salt of carbonic acid, characterized by the presence of the carbonate ion, CO2−3. The name may also mean an ester of carbonic acid, an organic compound containing the carbonate group O=C2 and silicate A silicate is a compound containing a silicon bearing anion. The great majority of silicates are oxides, but hexafluorosilicate and other anions are also included. This article focuses mainly on the Si-O anions. Silicates comprise the majority of the earth's crust, as well as most planets and moons. Sand, Portland cement, and thousands of minerals melts and by carbon dioxide Carbon dioxide is a chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state. CO2 is a trace gas comprising 0.039% of the atmosphere-rich and water-rich fluids, as discussed by Luth (2003). Metasomatism is thought to be particularly important in changing the composition of mantle peridotite below island arcs An island arc is a type of archipelago formed as one oceanic tectonic plate subducts under another and produces magma at depth below the over-riding plate. An island arc that develops along the edge of a continent may be known as a volcanic arc, though most people find the distinction of little benefit as water is driven out of ocean An ocean is a major body of saline water, and a principal component of the hydrosphere. Approximately 71% of the Earth's surface (~3.61 X 1014 m2) is covered by ocean, a continuous body of water that is customarily divided into several principal oceans and smaller seas lithosphere The lithosphere is the rigid outermost shell of a rocky planet. It comprises the crust and the portion of the upper mantle that behaves elastically on time scales of thousands of years or greater during subduction In geology, subduction is the process that takes place at convergent boundaries by which one tectonic plate moves under another tectonic plate, sinking into the Earth's mantle, as the plates converge. A subduction zone is an area on Earth where two tectonic plates move towards one another and subduction occurs. Rates of subduction are typically. Metasomatism has also been considered critical for enriching source regions of some silica-undersaturated magmas Magma [from Greek μάγμα, paste] is a mixture of molten rock, volatiles and solids that is found beneath the surface of the Earth, and may also exist on other terrestrial planets. Besides molten rock, magma may also contain suspended crystals and gas bubbles. Magma often collects in magma chambers that may feed a volcano or turn into a pluton. Carbonatite Carbonatites are intrusive or extrusive igneous rocks defined by mineralogic composition consisting of greater than 50 percent carbonate minerals. Carbonatites may be confused with marble, and may require geochemical verification melts are often considered to have been responsible for enrichment of mantle peridotite in incompatible elements During the fractional crystallization of magma, and magma generation by the partial melting of the Earth's mantle and crust, elements that have difficulty in entering cation sites of the minerals are concentrated in the melt phase of magma . An incompatible element is an element that is unsuitable in size and/or charge to the cation sites of the.

Contents

Types of metasomatites

Metasomatic rocks can be extremely varied. Often, metasomatised rocks are pervasively but weakly altered, such that the only evidence of alteration is bleaching, change in colour or change in the crystallinity of micaceous minerals.

In such cases, characterising alteration often requires microscope investigation of the mineral assemblage of the rocks to characterise the minerals, any additional mineral growth, changes in protolith minerals, and so on.

In some cases, geochemical evidence can be found of metasomatic alteration processes. This is usually in the form of mobile, soluble elements such as barium Barium is a chemical element. It has the symbol Ba, atomic number 56, and is the fifth element in Group 2. Barium is a soft silvery metallic alkaline earth metal. It is never found in nature in its pure form due to its reactivity with air. Its oxide is historically known as baryta but it reacts with water and carbon dioxide and is not found as a, strontium Strontium is a chemical element with the symbol Sr and the atomic number 38. An alkaline earth metal, strontium is a soft silver-white or yellowish metallic element that is highly reactive chemically. The metal turns yellow when exposed to air. It occurs naturally in the minerals celestine and strontianite. The 90Sr isotope is present in, rubidium Elemental rubidium is very soft and highly reactive, with properties similar to other elements in group 1, such as very rapid oxidation in air. Its compounds have chemical and electronic applications. Rubidium metal is easily vaporized and has a convenient spectral absorption range, making it a frequent target for laser manipulation of atoms, calcium Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth most abundant element by mass in the Earth's crust. Calcium is also the fifth most abundant dissolved ion in seawater by both molarity and mass, after sodium, chloride, and some rare earth elements As defined by IUPAC, rare earth elements or rare earth metals are a collection of seventeen chemical elements in the periodic table, namely scandium, yttrium, and the fifteen lanthanides. Scandium and yttrium are considered rare earths since they tend to occur in the same ore deposits as the lanthanides and exhibit similar chemical properties. However, to characterise the alteration properly, it is necessary to compare altered with unaltered samples.

When the process becomes extremely advanced, typical metasomatites can include:

Effects of metasomatism in mantle peridotite can be either modal or cryptic. In cryptic metasomatism, mineral compositions are changed, or introduced elements are concentrated on grain boundaries and the peridotite mineralogy appears unchanged. In modal metasomatism, new minerals are formed.

Cryptic metasomatism may be caused as rising or percolating melts interact with surrounding peridotite, and compositions of both melts and peridotite are changed. At high mantle temperatures, solid-state diffusion can also be effective in changing rock compositions over tens of centimeters adjacent to melt conduits: gradients in mineral composition adjacent to pyroxenite dikes may preserve evidence of the process.

Modal metasomatism may result in formation of amphibole and phlogopite, and the presence of these minerals in peridotite xenoliths has been considered strong evidence of metasomatic processes in the mantle. Formation of minerals less common in peridotite, such as dolomite, calcite, ilmenite, rutile, and armalcolite, is also attributed to melt or fluid metasomatism.

Alteration assemblages

Investigation of altered rocks in hydrothermal ore deposits has highlghted several ubiquitous types of alteration assemblages which create distinct groups of metasomatic alteration effects, textures and mineral assemblages.

Rarer types of hydrothermal fluids may include highly carbonic fluids, resulting in advanced carbonation reactions of the host rock typical of calc-silicates, and silica-hematite fluids resulting in production of jasperoids, manto ore deposits and pervasive zones of silicification, typically in dolomite formations.

References

See also

Categories: Metamorphic petrology | Geological processes

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